shiva-SBI Thanks for reporting this. In my experience multiple VPN profiles are not supported by iOS. Same issue with other VPN vendors. If you just use the one from the app store and then block access to corporate resources with Cato IP addresses that should work for you I believe.
Here is the global range for Cato IP addresses https://support.catonetworks.com/hc/en-us/articles/7784334332317-Production-PoP-Guide#h_01JKNFWT1BFH94DFEXSTBMCBK9
https://support.catonetworks.com/hc/en-us/articles/7784334332317-Production-PoP-Guide#h_01JKNFWT1BZZ65GRVBGZPV8JTT